Nitrile Rubber, frequently referred to as Buna-N, is a copolymer of butadiene and acrylonitrile. A number of polymers are commercially available with various monomer ratios. Those containing a high proportion of acrylonitrile have excellent resistance to petroleum oils and solvents, good tensile strength and abrasion resistance, but relatively poor low temperature flexibility. Decreasing acrylonitrile content yields great imrovement in the low temperature capability, but at the expense of poorer oil resistance. The most useful compounds are based on medium grades which effect a good balance of properties. Because of the generally good characteristics and a capability for being compounded to obtain a wide spectrum of specific properties, compounds of nitrile rubber find wide application in mechanical rubber goods.

Sample compound information:
5-228-70 / 5-457-60 / 5-488-70 / 5-2065-70 / 5-2067-90
5-2068-70 / 5-4067-70 / 5-4120-70 / 5-4200-70 / 5-4282-70
General Information for Nitrile Rubber

Compound Series: 5-200 to 5-299
5-2000 to 5-2899
5-400 to 5-499
5-4000 to 5-4999
Temperature Range (F): -65° to +300°
General Properties: Good resistance to petroleum hydrocarbons. Capable of wide compounding variations for specific properties.
Most Common Applications: Hydraulic actuator seals
Hydraulic pump seals
Water pump seals
Carburetor seals
Transmission seals
Relative Properties of Nitrile Rubber

Tensile Strength (psi)
-Pure Gum:
-Compounded Stocks:
Below 1000
Over 1500
Hardness Range:
(Shore Durometer A)
40 - 95
Specific Gravity:
(Base Material)
1.00
Vulcanizing Properties: Excellent
Adhesion to Metals: Excellent
Adhesion to Fabrics: Good
Tear Resistance: Fair
Abrasion Resistance: Good
Compression Set: Good
Rebound
-Cold:
-Hot:
Good
Good
Dielectric Strength: Poor
Electrical Insulation: Fair
Permeability to Gases: Medium
Temperature Range in Air (F): -65° to +250°
Acid Resistance
-Dilute:
-Concentrated:
Good
Good
Caustic Resistance: Fair
Solvent Resistance
-Aliphatic Hydrocarbons:
-Aromatic Hydrocarbons:
-Oxygenated (Keytones, etc.):
-Lacquer Solvents:
Excellent
Good
Poor
Fair
Resistance To
-Swelling in Lubricating Oil:
-Gasoline:
-Animal and Vegetable Oil:
-Water Absorption:
-Oxidation:
-Ozone:
-Sunlight Aging:
-Heat Aging:
-Flame:
-Heat:
-Cold:
Very good
Excellent
Excellent
Fair to Good
Good
Fair
Poor
Good
Poor
Excellent
Good


Nitrile Rubber (Buna-N)
5-228-70
: A gasoline-resistant compound for service where minimum swell in fuel is required. Listed by Underwriter's Lab. However, long dry-out periods subsequent to fuel immersion may result in undesirable shrinkage and may require seal replacement after idle storage of equipment. Shrinkage will occur in lubricating oils. Temperature range -40°F to +200°F.

Compound Number: 5-228-70
Use with: Gasoline
Kerosene
Naphtha
LPG
Fuel oil
Ammonia
Do not use with: Lube oil
Special Applications: Automotive fuel system seals
Temperature Range (F): -40° to +200°
Comments: U.L. listed for use with gasoline, kerosene, naphtha, LP-Gas, and anhydrous ammonia (both gaseous and liquid phase), and for use with fuel oil numbers 1 through 6 inclusive. Meets SAE 120R1, Class II. Recommended for continuous service in fuel. Intermittent service may result in dry-out, shrinkage or leakage.

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Nitrile Rubber (Buna-N)
5-457-60
: For service in aircraft fuel systems. Excellent resistance to non-aromatic fuels anf moderately good in blended aromatic fuels. Excellent low temperature flexibility which has been achieved with some necessary compromise of the resistance to aromatic fuel. Qualified to specification MIL-P-5315B. Temperature range -65°F to +200°F.

Compound Number: 5-457-60
Use with: Aviation fuels
Do not use with: Lube oil
Special Applications: Aviation fuel system seals
Temperature Range (F): -65° to +200°
Military Drawing Numbers: MS 29512
MS 29513
Comments: Qualified to spec. MIL-P-5315

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Nitrile Rubber (Buna-N)
5-488-70
: A general purpose material suitable for use in most petroleum oils and greases, automotive gasoline, alcohols and glycols, L-P gases, propane and butane, fuel oils and many other fluids. Listed by Underwriter's Lab. Good abrasion and compression set resistance. Temperature range -40°F to +300°F.

Compound Number: 5-488-70
Use with: Petroleum oils
Gasoline
Kerosene
Naphtha
LPG
Fuel oil
Ammonia
Special Applications: Automotive fuel system seals
Temperature Range (F): -40° to +250°
Comments: U.L. listed for use with gasoline, kerosene, naphtha, LP-Gas (both gaseous and liquid phase), and anhydrous ammonia (both gaseous and liquid phase).

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Nitrile Rubber (Buna-N)
5-2065-70


Compound Number: 5-2065-70
Use with: Petroleum oil
Freon 12
Do not use with: Freon 22
Special Applications: Refrigeration compression seals
Temperature Range (F): -40° to +300°

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Nitrile Rubber (Buna-N)
5-2067-90
: Specifically recommended for the most severe high pressure applications involving petroleum base fluids including crude oils. Temperature range is usually -30°F to +300°F, but this compound has endured intermittent exposure to +450°F in certain specialized oil tool applications.

Compound Number: 5-2067-90
Use with: Petroleum oils (including crude)
Water
Special Applications: Very high pressure seals
Oil tool seals
Temperature Range (F): -20° to +300°
Comments: Exceptional abrasion resistance (carboxylated nitrile) approaching that of urethane. Very resistant to seal extrusion at high pressures.

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Nitrile Rubber (Buna-N) for food
5-2068-70
: For food service, resistant to vegetable and animal oils and fats. This compound utilizes only compounding ingredients listed in the FDA "white list" as suitable for service in contact with foods. This is a black colored compound, but light colored equivalents may be obtained on special order. Temperature range -40°F to +280°F.

Compound Number: 5-2068-70
Use with: Water
Vegetable oils
Animal fats
Silicone oils
Special Applications: Food handling equipment
Temperature Range (F): -40° to +250°
Comments: Conforms to FDA requirements (except milk and edible oils).
Reference CFR 177.2600

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Nitrile Rubber (Buna-N)
5-4067-70
: For aircraft hydraulic system service in MIL-H-5606B fluid. Good low temperature flexibility. Qualified to specification MIL-P-25732B and MIL-P-5516C, Class B. Temperature range -65°F to +275°F.

Compound Number: 5-4067-70
Use with: MIL-H-5606 petroleum based aircraft hydraulic fluid ("red oil")
Special Applications: Military aircraft hydraulic seals
Temperature Range (F): -65° to +275°
Military Drawing Numbers: AN 6227B
AN 6230B
MS 28775
Comments: Qualified to spec. MIL-P-5516, Class B
Qualified to spec. MIL-P-25732

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Nitrile Rubber (Buna-N)
5-4120-70
: Excellent compound for severe automotive service. Resistant to lubricating oils, transmission fluids, greases and dry heat. Low compression set. Temperature range -40°F to +300°F.

Compound Number: 5-4120-70
Use with: Lube oil
Automatic transmission fluid
Engine coolant
Special Applications: Automatic transmission seals
Temperature Range (F): -40° to +300°
Comments: Meets spec. AMS 3228
Excellent compatibility with ABS, polycarbonate ans other stress-sensitive plastics.

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Nitrile Rubber (Buna-N)
5-4200-70
: An excellent general purpose nitrile rubber compound which conforms to the detail requirements of a variety of industrial specifications, including AMS 7270F and SAE J120a, Class I and Class II. Temperature range -40°F to +300°F. Listed by Underwriter's Lab for LPG service.

Compound Number: 5-4200-70
Use with: Petroleum oils
Engine coolant
Water
LPG
Temperature Range (F): -40° to +300°
Military Drawing Numbers: AN 123951 through AN 124050
Comments: Excellent general-purpose nitrile
U.L. listed for use with L-P Gas (liquid and gaseous phase) and for use in dry-chemical fire extinguisher applications
Meets spec. AMS 7270
Meets spec. AMS 3228
Meets spec. SAE 120 R1, Class I

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Nitrile Rubber (Buna-N)
5-4282-70
: Resistant to di-ester type synthetic lubricants used principally in jet aircraft applications. Qualified to specification MIL-R-7362D. Temperature range -40°F to +275°F.

Compound Number: 5-4282-70
Use with: Synthetic jet engine lube oil MIL-L-7808
Temperature Range (F): -50° to +250°
Military Drawing Numbers: MS 29561
Comments: Meets spec. MIL-R-7362
Specifically for use with aircraft jet engine lubricant

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